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{$('pic').src=imglist['url'][curnum+1];current_pic(curnum+1);}} next.title = ''; //cont.style.position = 'relative'; if(divappend == 1) { cont.appendChild(pager); pager.appendChild(pre); pager.appendChild(next); } } var onopen = 0; $('pic').onload = function(){ viewPhoto(); if(onopen == 0) { onopen = 1; } else { var imagepos = fetchOffset($('photo_pic')); document.documentElement.scrollTop = imagepos['top']; } } document.onkeyup = function(e){ e = e ? e : window.event; var tagname = BROWSER.ie ? e.srcElement.tagName : e.target.tagName; if(tagname == 'INPUT' || tagname == 'TEXTAREA') return; actualCode = e.keyCode ? e.keyCode : e.charCode; if(actualCode == 39) { $('pic-next').click(); } if(actualCode == 37) { $('pic-prev').click(); } } </script> <div id="p_btn" class="mtw mbm cl xs1" style="display:none;"> <a href="http://club.oecr.com/home.php?mod=spacecp&ac=share&type=thread&id=246015" id="k_share" onclick="showWindow(this.id, this.href, 'get', 0);" onmouseover="this.title = 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src="static/image/common/rec_subtract.gif" alt="反对" />反对<span id="recommendv_subtract">0</span></i></a> </div> </td> <td valign="top" class="album_side_r"> <div class="album_side"> <div class="hm mtn mbn"> <a href="http://club.oecr.com/space-uid-54876.html" target="_blank" class="xi2"><img src="http://www.oecr.com/uc_server/avatar.php?uid=54876&size=small" /></a> <span class="tit_author"> <a href="http://club.oecr.com/space-uid-54876.html">update</a> </span> </div> <div class="date"><span>发布时间:</span> 2011-9-14 15:36</div> <div class="album_info"> <h3>正文摘要: </h3> <p>试图模仿的光合作用系统，见于植物和一些细菌中，科学家们已经迈出了一步，开发出一种人工捕光系统（LHS：light-harvesting system），可以满足这种系统的关键要求之一：约100％的能量转移效率。对于开发有益的人工 ...</p> </div> </div> </td> </tr> </table> </div> </div> <div class="bm vw pl" id="comment"> <div class="bm_h cl"> <h2>回复</h2> </div> <div class="bm_c"> <div id="postlistreply" class="xld xlda mbm"><div id="post_new" class="viewthread_table" style="display: none"></div></div><div id="post_928585" class="xld xlda mbm"><dl class="bbda cl"> <dd class="m avt"><a href="http://club.oecr.com/space-uid-54876.html"><img src="http://www.oecr.com/uc_server/avatar.php?uid=54876&size=small" /></a></dd> <dt> <span class="y xw0"> </span> <a href="http://club.oecr.com/space-uid-54876.html" target="_blank" class="xi2">update</a><em id="author_928585"> 发表于</em> <span class="xg1 xw0">2011-9-14 15:36:56</span> </dt> <dd class="z"><div class="pcb"> <div class="t_fsz"> <table cellspacing="0" cellpadding="0"><tr><td class="t_f" id="postmessage_928585"> 在前人研究成果的基础上，科学家们选择使用两种类型的卟啉染料分子，以达到这个目的，这些分子他们排列在粘土表面。分子在粘土表面倾向于聚集或分隔，这是具有挑战性的，因为研究人员要排列这些分子，形成规则的模式，就像它们的自然对应物一样。<br /> <br /> “一种分子排列要具有适当的分子间距，这很重要，因为要达到近100％的能量转换效率，”高木说。“如果分子间的距离太近，其他反应如电子转移和光化学反应就会发生。如果分子间的距离太远，钝化的兴奋染料就会超过能量转换反应。”<br /> <br /> 为了达到适当的分子间距，科学家们开发出一种新的制备工艺，就是使卟啉分子中的带电荷基（charged sites）之间的距离，匹配粘土表面带负电荷（阴离子）基（negatively charged [anionic]sites）之间的距离。这种效果，研究人员称之为“大小匹配规则”，有助于抑制一些主要因素，就是使卟啉分子倾向于聚集或分隔的因素，并把分子固定在合适均匀的分子间距中。高木解释说，在形成分子模式时，这一策略显著不同于其他方法。<br /> <br /> “这一方法是独一无二的，”他说。“在通常自组装系统的情况下，形成这种排列，就需要客-客体相互作用（guest-guest interactions）。在我们的系统中，主客体相互作用（host-guest interactions）发挥了至关重要的作用，可实现特殊的染料排列。因此，通过改变主体材料，就可以控制粘土表面的染料分子排列。”<br /> <br /> 正如研究人员证明，规则排列的分子带来的激发能量转移效率高达100％。结果表明，卟啉染料分子和粘土主体材料看起来像是一种有希望的候选材料，可用于人工捕光系统。<br /> <br /> “目前，我们的系统只包含两种染料，”高木说。“下一步，必须结合几种染料来吸收所有阳光。我们系统的特征点之一，是很容易同时使用几种染料。因此，我们的系统是一种有希望的候选材料，可用于实际的捕光系统，利用所有的阳光。我们相信，即使是光化学反应部分，也可以结合在相同的粘土表面。如果这个系统制成了，结合光化学反应中心，这种系统就可以被称为“无机叶”。<br /> <br /> 更多信息：《高效激发能量转移反应用粘土/卟啉混合物制备人工捕光系统》（Efficient Excited Energy Transfer Reaction in Clay/Porphyrin Complex toward an Artificial Light-Harvesting System）。”《美国化学学会杂志》<br /> <br /> 原文链接：<a href="http://pubs.acs.org/doi/full/10.1021/ja204425u" target="_blank">http://pubs.acs.org/doi/full/10.1021/ja204425u</a></td></tr></table> </div> <div id="comment_928585" class="cm"> </div> <div 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