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onkeyup="$('fj_btn').href='forum.php?mod=redirect&ptid=270847&authorid=0&postno='+this.value" onkeydown="if(event.keyCode==13) {window.location=$('fj_btn').href;return false;}" title="跳转到指定楼层" /> <a href="javascript:;" id="fj_btn" class="z" title="跳转到指定楼层"><img src="static/image/common/fj_btn.png" alt="跳转到指定楼层" class="vm" /></a> </div> <strong> <a href="http://bbs.oecr.com/thread-270847-1-1.html" id="postnum1152411" onclick="setCopy(this.href, '帖子地址复制成功');return false;"> <em>1</em>楼</a> </strong> <div class="pti"> <div class="pdbt"> </div> <div class="authi"> <img class="authicn vm" id="authicon1152411" src="static/image/common/online_member.gif" /> <em id="authorposton1152411">发表于 2015-7-12 23:08:47</em> <span class="pipe">|</span> <a href="http://bbs.oecr.com/forum.php?mod=viewthread&tid=270847&page=1&authorid=12" rel="nofollow">只看该作者</a> <span class="none"><img src="static/image/common/arw_r.gif" class="vm" alt="回帖奖励" /></span> <span class="pipe show">|</span><a href="http://bbs.oecr.com/forum.php?mod=viewthread&tid=270847&extra=&ordertype=1" class="show">倒序浏览</a> <span class="pipe show">|</span><a href="javascript:;" onclick="readmode($('thread_subject').innerHTML, 1152411);" class="show">阅读模式</a> </div> </div> </div><div class="pct"><style type="text/css">.pcb{margin-right:0}</style><div class="pcb"> <div class="t_fsz"> <table cellspacing="0" cellpadding="0"><tr><td class="t_f" id="postmessage_1152411"> 一种全新的金属有机配合物非线性光学<a href="http://material.oecr.com" target="_blank" class="relatedlink">晶体</a>CdHg（SCN）4（C2H5NO）2的生长、物化和光学性能表征<br /> Growth,physicochemical and optical characterization of a novel organometallic nonlinear optical crystal：CdHg（SCN）_4（C_2H_5NO）_2<br /> 下载全文<br /> <ignore_js_op> <img src="static/image/filetype/pdf.gif" border="0" class="vm" alt="" /> <span style="white-space: nowrap" id="attach_88266" onmouseover="showMenu({'ctrlid':this.id,'pos':'12'})"> <a href="http://bbs.oecr.com/forum.php?mod=attachment&aid=ODgyNjZ8ZTc0N2RkNmJ8MTc2NTkyNjQ5MHwwfDI3MDg0Nw%3D%3D" target="_blank">一种全新的金属有机配合物非线性光学晶体CdHg（SCN）4（C2H5NO）2的生长、物化和光学.pdf</a> <em class="xg1">(296.03 KB, 下载次数: 0)</em> </span> <div class="tip tip_4" id="attach_88266_menu" style="position: absolute; display: none" disautofocus="true"> <div class="tip_c xs0"> <div class="y">2015-7-12 23:08 上传</div> 点击文件名下载附件 <br />下载积分: 光电贝 -10 元 </div> <div class="tip_horn"></div> </div> </ignore_js_op> <br /> 作 者：刘雪松 刘希涛 王新强<br /> LIU Xue-song, LIU Xi-tao, WANG Xin-qiang （State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Ji~ nan 250100,China）<br /> 机构地区：山东大学晶体<a href="http://material.oecr.com" target="_blank" class="relatedlink">材料</a>国家重点实验室,晶体材料研究所<br /> 出 处：《功能材料》 EI CSCD 2014年第45卷第12期 12055-12059页,共5页<br /> Journal of Functional Materials<br /> 基 金：山东省优秀中青年科学家科研奖励基金资助项目（BS2011CL025）<br /> 摘 要：在以水和N-甲基甲酰胺的混合溶剂中制备了一种潜在的二阶非线性光学晶体：二N-甲基甲酰胺合硫氰酸汞镉（CdHg（SCN）4（C2H5NO）2（CMTN））;用溶液降温法生长出了尺寸为30 mm×27 mm×9mm的较高光学质量的单晶体。采用元素分析、粉末衍射、红外和拉曼光谱、热分析和紫外/可见/近红外透过光谱表征了它的结构、<a href="http://theory.oecr.com" target="_blank" class="relatedlink">物理</a>化学、热分解和光学性质。该晶体在128.5℃开始分解,其紫外截止波长为358nm。<br /> A novel potentially useful second harmonic generation（SHG）organometallic nonlinear optical crystal：cadmium mercury thiocyanate bis（N-methylformamide）,CdHg（SCN）4（C2H5NO）2（CMTN）has been prepared,and large highly-optical quality single crystals with dimensions up to 30mm×27mm×9mm have been grown by the temperature-lowering method.The structural,physicochemical,thermal decomposition and optical properties are characterized by elemental analyses,X-ray powder diffraction,Fourier transform infrared and Raman spectroscopy,thermal analysis and UV/Vis/NIR transmission.CMTN possesses good physicochemical stabilities up to 128.5℃,and the UV transparency cutoff was 358nm.<br /> 关键词：金属有机配合物 非线性光学晶体 CdHg（SCN）4（C2H5NO）2 溶液法生长 表征<br /> organometallic compounds ;nonlinear optical crystals ;CdHg（SCN）4（C2H5NO） ;growth from solutions ;characterization ;</td></tr></table> <div class="ptg mbm mtn"> <a title="University" href="misc.php?mod=tag&id=2842" target="_blank">University</a>, <a title="山东大学" href="misc.php?mod=tag&id=6188" target="_blank">山东大学</a>, <a title="Journal" href="misc.php?mod=tag&id=6708" target="_blank">Journal</a>, <a title="Crystal" href="misc.php?mod=tag&id=3896" target="_blank">Crystal</a>, <a title="crystal" href="misc.php?mod=tag&id=3896" target="_blank">crystal</a></div> </div> <div id="comment_1152411" class="cm"> </div> <div id="post_rate_div_1152411"></div> </div> </div> <div class="cm"> <h3 class="psth xs1"><span class="icon_ring vm"></span>本帖被以下淘专辑推荐:</h3> <ul class="mbw xl xl2 cl"><li>· <a href="http://bbs.oecr.com/forum.php?mod=collection&action=view&ctid=14" title="光电材料之光学晶体" target="_blank" class="xi2 xw1">光电材料之光学晶体</a><span class="pipe">|</span><span class="xg1">主题: 22, 订阅: 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